100030021

MITIGATION OF DELAYED ETTRINGITE FORMATION USING
CLASS F FLY ASH OR MIX WATER CONDITIONER
Conference
30th Our World in Concrete and Structures (OWICs) - 2005
Authors
A M Amde*, University of Maryland, USA
A Azzam, District Department of Transportation, USA
R A Livingston, Federal Highway Administration, USA
Handle
100030021
Key Words
Ettringite, delayed ettringite formation, DEF, fly ash, mix water conditioner,
concrete durability
Abstract
The effects on delayed ettringite formation (DEF) of partially replacing the
Portland cement by different amounts Class F fly ash or using mix water
conditioners (MWC) are discussed. Recent studies have shown that DEF may be
associated with deterioration problems in concrete. Many countries have reported
deterioration of concrete structures where the main cause of distress has been
identified as DEF. The results presented in this paper are part of an on going
comprehensive study on DEF that is being conducted at the University of
Maryland in collaboration with the Federal Highway Administration. The study has
involved numerous parameters. Quantitative X-ray diffraction (QXRD) and
scanning electron microscope (SEM) equipped with a high-energy dispersive Xray
analysis (EDAX) methods were used to identify materials in the cavities,
transition zones and cracks to determine the mechanism of concrete failure. The
X-ray computed tomography (CT) method was employed to reveal interior cracks.
Heat cycles and other techniques were used to accelerate the test. The results
showed formation of ettringite crystals in cavities, in the interface between
aggregate and cement paste, etc. Partially replacing the Portland cement with
Class F fly ash decreased the expansion, with specimens showing larger
reductions as the percentage of fly ash increased. The SEM results correlated
with the observed expansions. The effect of using MWC was found to be similar
to using 10% fly ash with respect to expansion but not with respect to
compressive strength. The short term and long term effects on compressive
strength were also investigated.
Full Text
100030021
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